Last year, companies came forward with oyster shells, wood pulp, rice husk ash and even tomatoes as sustainable alternatives to fossil-based feedstocks. While oysters and tomatoes didn't make a reappearance on the menu this year, companies' appetites for bio-based feedstocks—some familiar, some new—haven't been lost yet.
Milin Environmental Inc. brought a new material to its portfolio, which it showcased at the International Elastomer Conference this fall: rice husk ash silica.
The company, which already has offered devulcanized reclaim, such as butyl, chlorobutyl, EPDM and whole tire rubber, became the exclusive North American distributor of rice husk ash silica produced by its partner, Gujrat, India-based Brisil Technologies Pvt. Ltd.
Milin President Ryan Heffernan told Rubber News at the conference that the material had "been very well received," even by companies it didn't expect to be interested.
And a wood-based byproduct made its way into the industry again when, in February, Resolo A.B. made the case for birch bark as a sustainable alternative for rubber.
The Swedish company won Nokian Tyres P.L.C.'s annual "Fast Race, Big Change" sustainable tire innovation challenge for its renewable rubber that utilizes birch bark. According to Resolo, the bark is sourced from the residue of the global pulp, paper and plywood industry, noting a single mill creates 100,000 tons of birch bark residue annually.
The forestry industries in Finland and Sweden alone produce enough raw material for 200,000 tons of Resolo's rubber, according to the company.
Other companies looked to partnerships to further their bio-based goals.
Early in the year, Teknor Apex launched an eco-conscious Monprene thermoplastic elastomer in partnership with UBQ Materials. The TPE, Monprene S3 CP-15170 BLK, is made with 35-percent sustainable content, including post-consumer recycled materials, as well as new material, UBQ.
The patented UBQ is "the world's first bio-based thermoplastic" made from organic and unrecyclable waste. It replaces oil-based materials and diverts municipal solid waste from landfills, according to the two companies.
Kolon Industries Inc. partnered with a forestry company, Helsinki, Finland-based Stora Enso Oyj, in the spring to industrialize the production of bio-based polyesters for use in tire cords.
Through their joint development agreement, the two companies plan to industrialize Stora's proprietary process to produce furandicarboxylic acid (FDCA) and 5-hydroxymethylfurfural (HMF), both of which can be used as feedstock in the production of bio-polyesters like polyethylene furanoate.
Kumho Petrochemical joined forces with styrene monomer manufacturer Idemitsu and Sumitomo Corp. to create a "biomaterial" supply chain. The trio signed a long-term memorandum of understanding to develop sustainable polymers and chemicals in Asia, according to Sumitomo.
As part of the project, Idemitsu will produce bio-based styrene monomer, based on the mass balance method, and Kumho Petrochemical will produce bio-solution styrene butadiene rubber, a key material for high-functional tires, using bio-styrene monomer.
Goodyear partnered with Hayward, Calif.-based Visolis Inc. in the fall, which uses synthetic biology to manufacture high-performance, carbon-negative materials.
Together, Goodyear said, the companies will collaborate on bio-based isoprene. This would then be used to produce polyisoprene, a foundational material for tires and other applications. While isoprene is typically developed from the refinement of crude oil, Visolis uses proprietary technology to generate the material from bio-waste, such as "lignocellulosic" feedstocks.
"We are excited to collaborate with Goodyear and leverage our revolutionary technology to transform waste materials into valuable monomers," Visolis CEO Deepak Dugar said at the time, noting the partnership with Goodyear was a "testament to our shared commitment to sustainable practices and the development of advanced materials that drive positive change."
And just in November, two companies brought forward bio-based developments in the urethanes sector.
Trelleborg announced its partnership with Algenesis Materials for the development of a sustainable TPU for the Swedish giant's fabric coating applications. Algenesis developed TPUs derived from raw materials based on algae and non-food plants, according to Trelleborg, that perform similarly to existing products while also being biodegradable.
And Henkel A.G. claims its new bio-based, wood adhesives reduce CO2 emissions by more than 60 percent compared to their fossil-based counterparts. The polyurethane-based adhesives, HB S Eco and CR 821 Eco, are variants of the company's Loctite engineered wood adhesives for load-bearing timber construction.
HB S Eco, a one-component PU adhesive, is made using 63-percent bio-based materials, is certified according to the ISCC Plus mass balance method and generates 66-percent lower CO2 emissions. CR 821 Eco, is a bio-based two-component PU resin that includes 71-percent bio-based materials, is partly ISCC Plus certified, and gives a 62-percent reduction in CO2 emissions.