As the newest zinc oxide plant in the U.S. by 20 years, "Zochem South" has become well-versed in the operation of muffled furnaces, which use "conductive refractory and low nitrous oxide natural gas burners to create a uniform temperature profile over a large molten metal bath."
Sharma said very few zinc oxide producers use muffle furnaces, with a majority using the less efficient crucible technology, "like a big pot on a stove."
"I do not claim to be an expert on crucible technology, but there are just a couple suppliers using muffle furnaces, while there are hundreds using crucibles," Sharma said, adding the crucible furnaces can be installed for $1 million or less.
So what makes muffle furnaces more environmentally friendly?
Essentially crucible furnaces are a melting pot, while a muffle furnace is a 40-foot-by-20-foot apparatus with much larger molten metal baths, which offer much more available surface area to vaporize zinc metal.
In addition, the design allows for better transmission of heat (generated by natural gas for Zochem) and conducts better in this closed-capsule environment.
And the heat source itself, Sharma said, never touches the metal, as muffle furnaces provide an indirect heat conducted through a refractory arch made of silicon carbide, which itself conducts heat to the bath.
"They are designed with minimal heat loss and high conductivity, which allows for more sustainable operations from an output standpoint—if a million BTUs are pumped into the furnace, the heat is more efficiently used, allowing companies to produce more product," he said.
Zochem produces zinc oxide by the French process, an indirect process whereby zinc metal is placed in a solid form into the huge muffle furnaces and heated to a molten form. The molten zinc then is boiled in a different furnace, and the boiling zinc ultimately is introduced to ambient air.
At that point the zinc self-ignites and forms zinc oxide, a fine white powder that can be distributed as is, or in pellet form.
While about 40 percent of the total zinc oxide market (from all producers of zinc oxide) in North America goes toward the rubber tire industry, the compound also can be found in motor oil and transmission fluid, dental care products, sunscreens, fertilizers, livestock feeds, over-the-counter flu remedies, vitamins, tile glazes, paints, food additives and even electronics.
For any rubber compound, zinc oxide acts as an activator for vulcanization, adding strength and improving a compound's resistance to heat, abrasion and ultraviolet degradation.