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Datwyler opens Delaware plant
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MIDDLETOWN, Del.—The sealing unit of Datwyler Holding A.G. celebrated the grand opening of its new medical manufacturing plant in Middletown. The site represents a $100 million investment,...
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MIDDLETOWN, Del.—The sealing unit of Datwyler Holding celebrated the grand opening of its new medical manufacturing plant in Middletown. MIDDLETOWN, Del.—The sealing unit of Datwyler Holding celebrated the grand opening of its new medical manufacturing plant in Middletown. $MIDDLETOWN, Del.—The sealing unit of Datwyler Holding celebrated the grand opening of its new medical manufacturing plant in Middletown.
Yokohama to combine R&D efforts into new center
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CORNELIUS, N.C.—Yokohama Tire Corp. has opened a new research and development facility in Cornelius, designed to bring together its R&D efforts into one location.Yokohama Development...
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CORNELIUS, N.C.—Yokohama has opened a new research and development facility in Cornelius, designed to bring together its research and development efforts into one location. CORNELIUS, N.C.—Yokohama has opened a new research and development facility in Cornelius, designed to bring together its research and development efforts into one location. $CORNELIUS, N.C.—Yokohama has opened a new research and development facility in Cornelius, designed to bring together its research and development efforts into one location.
Photos: Goodyear tires drive NASCAR tradition
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AKRON—The first thing you sense while you tour the Goodyear Innovation Center Manufacturing facility in Akron is the enormous amount of pride, workmanship and know-how that goes into each of ...
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AKRON—The first thing you sense while you tour the Goodyear Innovation Center Manufacturing facility in Akron is the enormous amount of pride, workmanship and know-how that goes into each of the 4,000-plus racing tires. AKRON—The first thing you sense while you tour the Goodyear Innovation Center Manufacturing facility in Akron is the enormous amount of pride, workmanship and know-how that goes into each of the 4,000-plus racing tires. $AKRON—The first thing you sense while you tour the Goodyear Innovation Center Manufacturing facility in Akron is the enormous amount of pride, workmanship and know-how that goes into each of the 4,000-plus racing tires.
Electrification shaking up rubber auto parts sector
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Electrification is shaking up the automotive parts supply-chain: forcing rubber product companies to add new capabilities to their established areas of expertise in materials science and...
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Electrification is shaking up the automotive parts supply-chain: forcing rubber product companies to add new capabilities to their established areas of expertise in materials science and technology. Electrification is shaking up the automotive parts supply-chain: forcing rubber product companies to add new capabilities to their established areas of expertise in materials science and technology. $Electrification is shaking up the automotive parts supply-chain: forcing rubber product companies to add new capabilities to their established areas of expertise in materials science and technology.
Evonik opens tire silicas plant in South Carolina
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GOOSE CREEK, S.C.—Evonik Industries has inaugurated a precipitated silica plant in South Carolina, aimed at better serving the U.S. tire industry.The $120 million investment comes in...
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GOOSE CREEK, S.C.—Evonik Industries has inaugurated a precipitated silica plant in South Carolina, aimed at better serving the U.S. tire industry. GOOSE CREEK, S.C.—Evonik Industries has inaugurated a precipitated silica plant in South Carolina, aimed at better serving the U.S. tire industry. $GOOSE CREEK, S.C.—Evonik Industries has inaugurated a precipitated silica plant in South Carolina, aimed at better serving the U.S. tire industry.
Long development journey pays off for Tweel, Michelin
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AKRON—For the record, Michelin's Steve Cron isn't a big fan of the name given to the product that has defined much of his 30-year career in the tire industry. That product is the Tweel, the ...
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AKRON—For the record, Michelin's Steve Cron isn't a big fan of the name given to the product that has defined much of his 30-year career in the tire industry. That product is the Tweel, the tire maker's easily recognizable product that combines a non-pneumatic tire with a polyurethane spoked wheel. AKRON—For the record, Michelin's Steve Cron isn't a big fan of the name given to the product that has defined much of his 30-year career in the tire industry. That product is the Tweel, the tire maker's easily recognizable product that combines a non-pneumatic tire with a polyurethane spoked wheel. $AKRON—For the record, Michelin's Steve Cron isn't a big fan of the name given to the product that has defined much of his 30-year career in the tire industry. That product is the Tweel, the tire maker's easily recognizable product that combines a non-pneumatic tire with a polyurethane spoked wheel.
Old Dana taps the fountain of youth
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MAUMEE, Ohio—With little fanfare this year, one of the global auto industry's oldest suppliers began repositioning itself for a business of the future. Dana Inc. has made two key...
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MAUMEE, Ohio—With little fanfare this year, one of the global auto industry's oldest suppliers began repositioning itself for a business of the future. MAUMEE, Ohio—With little fanfare this year, one of the global auto industry's oldest suppliers began repositioning itself for a business of the future. $MAUMEE, Ohio—With little fanfare this year, one of the global auto industry's oldest suppliers began repositioning itself for a business of the future.
Kent Elastomer to expand headquarters
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KENT, Ohio—Kent Elastomer Products Inc. is expanding its headquarters to accommodate its growing work force.The firm broke ground on an extension to the office area of its Kent facility,...
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KENT, Ohio—Kent Elastomer Products is expanding its headquarters to accommodate its growing work force. KENT, Ohio—Kent Elastomer Products is expanding its headquarters to accommodate its growing work force. $KENT, Ohio—Kent Elastomer Products is expanding its headquarters to accommodate its growing work force.
Private equity firm KKR set to acquire Minnesota Rubber & Plastics
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MINNEAPOLIS—Norwest Equity Partners has agreed to sell Quadion L.L.C., which does business as Minnesota Rubber & Plastics, to global investment firm KKR & Co. L.P. Terms of the...
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MINNEAPOLIS—Norwest Equity Partners has agreed to sell Quadion, which does business as Minnesota Rubber & Plastics, to global investment firm KKR. MINNEAPOLIS—Norwest Equity Partners has agreed to sell Quadion, which does business as Minnesota Rubber & Plastics, to global investment firm KKR. $ MINNEAPOLIS—Norwest Equity Partners has agreed to sell Quadion, which does business as Minnesota Rubber & Plastics, to global investment firm KKR.
Video: Miller calls Louisville Rubber Division meeting a success LOUISVILLE, Ky.—This week's ACS Rubber Division's International Elastomer Conference has been a success on all levels, according to Executive Director Ed Miller. LOUISVILLE, Ky.—This week's ACS Rubber Division's International Elastomer Conference has been a success on all levels, according to Executive Director Ed Miller. $LOUISVILLE, Ky.—This week's ACS Rubber Division's International Elastomer Conference has been a success on all levels, according to Executive Director Ed Miller.
Digital Edition
Digital Edition
Published on January 1, 2006

Controlled Radical Miniemulsion Polymerization

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Date Published January 1, 2006
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This Report has been authored by:F. Joseph Schork at Georgia Institute of Technology #with# James P. Russum at Georgia Institute of Technology #with# Wilfred Smulders at Georgia Institute of Technology #with# Christopher W. Jones at Georgia Institute of Technology

The advent of controlled radical polymerizations (CRP) has provided a potential means by which polymers of well-defined architecture can be synthesized using more forgiving and robust free-radical chemistry. Because of its versatility, we have chosen to use RAFT chemistry for CRP. Most work in CRP has been in solution polymerization; however, the adaptation of this chemistry to latex (emulsion and miniemulsion) systems has been reported. To date, the overwhelming majority of published research of CRP in miniemulsion has been directed at batch systems. Even so, continuous systems offer possibilities for polymer structure control that cannot be realized in batch systems. By combining stirred and tubular reactors in a train, one can in principle dictate the structure of the final copolymer, allowing for the use of process design to carry out molecular design or “product by process.” In this paper, we will discuss the use of batch, semibatch and continuous (stirred tank and tubular) reactors to create unique molecular and supramolecular architectures from conventional monomers using miniemulsion polymerization. 
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