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Autonomous technology driving vehicle design
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TROY, Mich.—Mobility always has been at the core of the automotive industry, and now it's also about to rock that same core. Autonomous vehicles are on the horizon. And even if that horizon ...
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TROY, Mich.—Autonomous vehicles are on the horizon. And even if that horizon is distant, the industry is preparing to design a new world where millions of people would gain access to the road if the technology can be brought to the mainstream. TROY, Mich.—Autonomous vehicles are on the horizon. And even if that horizon is distant, the industry is preparing to design a new world where millions of people would gain access to the road if the technology can be brought to the mainstream. $ TROY, Mich.—Autonomous vehicles are on the horizon. And even if that horizon is distant, the industry is preparing to design a new world where millions of people would gain access to the road if the technology can be brought to the mainstream.
Rubber rankings top 6 unchanged, but sales slide
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The top echelon of the North American rubber product manufacturing industry stayed intact during 2016, with the top six firms holding the same spots as 2015 and only one newcomer to the top 10....
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The top echelon of the North American rubber product manufacturing industry stayed intact during 2016, with the top six firms holding the same spots as 2015 and only one newcomer to the top 10. The top echelon of the North American rubber product manufacturing industry stayed intact during 2016, with the top six firms holding the same spots as 2015 and only one newcomer to the top 10. $The top echelon of the North American rubber product manufacturing industry stayed intact during 2016, with the top six firms holding the same spots as 2015 and only one newcomer to the top 10.
Arab investment firm partners with Nexen
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ABU DHABI, United Arab Emirates—Mubadala Investment Co., an Abu Dhabi-based strategic investment fund, has made an equity investment in Nexen Tire Corp. and struck a deal with the South...
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ABU DHABI, United Arab Emirates—Mubadala Investment has made an equity investment in Nexen and struck a deal with the South Korean tire maker to "explore strategic partnership opportunities." ABU DHABI, United Arab Emirates—Mubadala Investment has made an equity investment in Nexen and struck a deal with the South Korean tire maker to "explore strategic partnership opportunities." $ABU DHABI, United Arab Emirates—Mubadala Investment has made an equity investment in Nexen and struck a deal with the South Korean tire maker to "explore strategic partnership opportunities."
Business, labor groups react to USTR's NAFTA priorities
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WASHINGTON—A modernized North American Free Trade Agreement, ensuring the highest fair trade standards covering the broadest possible range of goods and services, is the Trump...
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WASHINGTON—The Office of the U.S. Trade Representative released its "Summary of Objectives for the NAFTA Renegotiation." The document was greeted by a wide range of comments from organizations and associations. WASHINGTON—The Office of the U.S. Trade Representative released its "Summary of Objectives for the NAFTA Renegotiation." The document was greeted by a wide range of comments from organizations and associations. $WASHINGTON—The Office of the U.S. Trade Representative released its "Summary of Objectives for the NAFTA Renegotiation." The document was greeted by a wide range of comments from organizations and associations.
Nexen sponsoring Euro soccer teams' U.S. tour
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SEOUL, South Korea—Nexen will be a sponsor of the 2017 International Champions Cup tour, which features a dozen matches between leading European soccer teams at U.S. stadiums July 19-30....
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SEOUL, South Korea—Nexen will be a sponsor of the 2017 International Champions Cup tour, which features a dozen matches between leading European soccer teams at U.S. stadiums. SEOUL, South Korea—Nexen will be a sponsor of the 2017 International Champions Cup tour, which features a dozen matches between leading European soccer teams at U.S. stadiums. $SEOUL, South Korea—Nexen will be a sponsor of the 2017 International Champions Cup tour, which features a dozen matches between leading European soccer teams at U.S. stadiums.
Toyoda Gosei expands Fluid Systems unit
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BRIGHTON, Mich.—A Toyoda Gosei Co. Ltd. subsidiary is about to get a whole lot bigger.TG Fluid Systems USA Corp. has begun construction of a 62,000-sq.-ft. addition to its manufacturing...
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BRIGHTON, Mich.—A Toyoda Gosei subsidiary is about to get a whole lot bigger with a 62,000-sq.-ft. addition. BRIGHTON, Mich.—A Toyoda Gosei subsidiary is about to get a whole lot bigger with a 62,000-sq.-ft. addition. $BRIGHTON, Mich.—A Toyoda Gosei subsidiary is about to get a whole lot bigger with a 62,000-sq.-ft. addition.
Bridgestone invests in proactive ride technology with ClearMotion
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NASHVILLE, Tenn.—Bridgestone Americas Inc. has invested in ClearMotion Inc. to incorporate road-sensing technology into its products to build a smoother ride. Bridgestone will work with...
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NASHVILLE, Tenn.—Bridgestone Americas has invested in ClearMotion to incorporate road-sensing technology into its products to build a smoother ride. NASHVILLE, Tenn.—Bridgestone Americas has invested in ClearMotion to incorporate road-sensing technology into its products to build a smoother ride. $NASHVILLE, Tenn.—Bridgestone Americas has invested in ClearMotion to incorporate road-sensing technology into its products to build a smoother ride.
Editorial: Both sides presented plausible accounts to ITC in ESBR case
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The investigation of emulsion SBR imports at the International Trade Commission featured a fairly typical set of plausible but mutually exclusive arguments. Lion Elastomers L.L.C., the one...
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The rubber industry is a complex one, ruled by proprietary research and development, delicate deal making, and an unavoidable, unpredictable human factor. The rubber industry is a complex one, ruled by proprietary research and development, delicate deal making, and an unavoidable, unpredictable human factor. $The rubber industry is a complex one, ruled by proprietary research and development, delicate deal making, and an unavoidable, unpredictable human factor.
Sentury picks Ohio design firm for Georgia plant
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LAGRANGE, Ga.—Qingdao Sentury Tire Co. Ltd. has selected SSOE Group of Toledo, Ohio, to design the $530 million, 1.4 million-sq.-ft. tire plant it's planning to build in LaGrange. Sentury...
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LAGRANGE, Ga.—Sentury has selected SSOE Group of Toledo, Ohio, to design the $530 million, 1.4 million-sq.-ft. tire plant it's planning to build in LaGrange. LAGRANGE, Ga.—Sentury has selected SSOE Group of Toledo, Ohio, to design the $530 million, 1.4 million-sq.-ft. tire plant it's planning to build in LaGrange. $LAGRANGE, Ga.—Sentury has selected SSOE Group of Toledo, Ohio, to design the $530 million, 1.4 million-sq.-ft. tire plant it's planning to build in LaGrange.
Firms propose to strengthen NAFTA
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WASHINGTON—With renegotiation of the North American Free Trade Agreement on the horizon, both Mexican and U.S. business interests, including the tire and auto parts industries, want to...
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WASHINGTON—With renegotiation of the North American Free Trade Agreement on the horizon, both Mexican and U.S. business interests, including the tire and auto parts industries, want to ensure that NAFTA is updated and strengthened, not repealed or fatally weakened. WASHINGTON—With renegotiation of the North American Free Trade Agreement on the horizon, both Mexican and U.S. business interests, including the tire and auto parts industries, want to ensure that NAFTA is updated and strengthened, not repealed or fatally weakened. $WASHINGTON—With renegotiation of the North American Free Trade Agreement on the horizon, both Mexican and U.S. business interests, including the tire and auto parts industries, want to ensure that NAFTA is updated and strengthened, not repealed or fatally weakened.
Digital Edition
Digital Edition
Published on January 1, 2006

Controlled Radical Miniemulsion Polymerization

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Date Published January 1, 2006
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This Report has been authored by:F. Joseph Schork at Georgia Institute of Technology #with# James P. Russum at Georgia Institute of Technology #with# Wilfred Smulders at Georgia Institute of Technology #with# Christopher W. Jones at Georgia Institute of Technology

The advent of controlled radical polymerizations (CRP) has provided a potential means by which polymers of well-defined architecture can be synthesized using more forgiving and robust free-radical chemistry. Because of its versatility, we have chosen to use RAFT chemistry for CRP. Most work in CRP has been in solution polymerization; however, the adaptation of this chemistry to latex (emulsion and miniemulsion) systems has been reported. To date, the overwhelming majority of published research of CRP in miniemulsion has been directed at batch systems. Even so, continuous systems offer possibilities for polymer structure control that cannot be realized in batch systems. By combining stirred and tubular reactors in a train, one can in principle dictate the structure of the final copolymer, allowing for the use of process design to carry out molecular design or “product by process.” In this paper, we will discuss the use of batch, semibatch and continuous (stirred tank and tubular) reactors to create unique molecular and supramolecular architectures from conventional monomers using miniemulsion polymerization. 
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